The Lakota word mahto (in some modern orthographies written matho) is generic for any kind of bear, male or female. The word for little is chinchala, so mahto chinchala is "little bear" of either sex.
In order to emphatically specify a female bear you would need to add winyela, which can be used of humans or animals; if you are thinking about a female human being with the name "Little Bear" you would have to add -win to the end of the name.
So:
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There is no such word in any of the Sioux dialects, so it has no meaning.
Sioux leaders were Red Cloud, Crazy Horse and Sitting Bull
Little Bear is wearing clothing of an Iroquois. Little Bear was from 1761. The actor that played Little Bear in the movie was a native American but not an Iroquois.
The achievements of the Sioux Indians was the Battle of Little Big Horn, where the Sioux Indians at an Indian camp fought off early American forces when they tried to take their territory.
Sioux is not a language but a group of related dialects.Chante is the Lakota word for heart. Wichachante is a human heart.The n indicates that the preceding vowing is nasalised.