It's probably George. It was established in an NCIS LA episode that his grandfather's name was George, and it's common for people to name their kids after their parents. So it's very possible that Callen's first name is George.
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His legal name is G. Callen. He does not know his true first name because no one has ever told him. This is because his parents left him when he was a kid and all he ever found out was it started with a G. So thus his name is G. Callen.
The name of his character in NCIS Los Angeles is G Callen. His real name is Chris O'Donnell. He is the head of the NCIS team in Los Angeles and reports to Hetty. He is similar to the Gibbs character in original NCIS but isn't so senior to the other characters. So, he shares a friendly kind of rapport with other characters.
Yes, Sasha Alexander plays Agent Todd in the first two seasons of NCIS.
special agent Caitlin "kate" todd she got killed off on the finale of the second series.
That would be detective Marty Deeks from LAPD or Agent Girodonno(sp.)from u.s. treasury
Hetty is the Operations Manager at NCIS in Los Angeles.