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Scott McCall becomes an alpha in the "Teen Wolf" episode titled "Alpha," which is the 12th episode of Season 3. In this episode, Scott is bitten by Deucalion, the leader of the alpha pack, and subsequently becomes an alpha himself. This transformation significantly impacts his character and the dynamics of the series moving forward.
Peter bit Scott. You will see that in season 1 episode 11
Yes. At the end of the first season Alison and Scott do get back together.
Scott's parents are divorced. You first see his father in Season 3, Episode 11 "Alpha Pact".
So far there are three wolves; two beta's and one alpha. The "teen wolf", who is a beta is Scott McCall, played by Tyler Posey. The second beta is Derek Hale, played by Tyler Hoechlin. The alpha is Derek Hale's uncle.