The most recent episode would be season 4 episode 12 Guilty as Charged. He's shot towards the end and the plot line picks up with the next episode Eyes Open.
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The character on Burn Notice that died was Madeline (Maddie) Weston. The actor who portrayed this character is Sharon Gless.
The title of the episode was "Who Shot Mr. Burns? Part 1."
doggeball episode
Detective Ed Green is shot in the episode called 'Burn Card' (season 18, episode 14), originally aired on 4/23/08. Jesse L. Martin appeared as Detective Green in 198 episode of Law and Order, 1 episode (2005) of Law and Order: Trial by Jury, 1 episode (2001) of Law and Order CI, and 2 episodes (1999-2000) of Law and Order SVU.
he got shot in season 7 and 8 : season 8 ep Episode 3 The Gunk in the Garage season 7 not sure what ep but he is shot