To my knowledge the Double Hit Orb is used to evolve Aipom into Ambipom.
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It boosts all attacks by up to 30%, but at the cost of some HP on each hit.
First of all, they are called the Lustrous orb and adamant orb. The adamant orb, when given to Dialga, boosts his power. Likewise the lustrous orb boosts the power of Palkia.
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The Flame Orb burns the user, and Burn lowers the attack of a Pokemon by one stage. This can be to your advantage, as you can some how give the Flame Orb you are holding to opponent, such as a Lopunny with Klutz and uses the move Switcheroo.
You can get a blue, green, red, pale, and prism orb underground.