No, if unless you are planning not to catch any other legendary pokemon. Zekrom is the easiest legendary to catch, you should use it later with kyurem which is level 75 and seems impossible to catch even with 1hp and put to sleep
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you should use it on lugia. he is the hardest one to catch. you cant catch him with any other pokeball. you can only catch him with a master ball.
Answer:Well pay close attention i think you should use it on an ancient Pokemon not just ordinary Pokemon because ordinary Pokemon can be caught with an ultra ball But if you ask me when you come across a Pokemon that you want and LOVE and it cant be caught with an ultra ball use an masterball !!!!!! I did the same thing and it tottally worked i caught a azelf with my master ball and i caught a uxie with an ultra ball ( SIMPLE MAKE IT WEAK) and ive been trying to catch mesprit since but takes a while!!
Either weakening its HP or using a Master ball, but i recommend you use a master ball.
Any Pokeball works the same for any Pokemon type. Legends like Zekrom, Thudurus, and Zapdos will require a higher ranked Pokeball, however; such as an Ultra Ball, Timer Ball, and Master Ball, if you don't want to wait.
After defeating him in the galactic HQ after the seventh gym, Cyrus will give you a master ball. Do not use your master ball on dialga! Instead, use it on Cresselia or another harder Pokemon to catch.