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The French were the first to use gas. In the first month of the war, August 1914, they fired teargas grenades (xylyl bromide) against the Germans.

The German Army used gas shells in the battle at Neuve Chappelle

The first use by the British was at Loos in September 1915 with the unfortunate result of the gas blowing back to their lines due to the wind changing direction.

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Q: What ww1 battles were poison gas used in?
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