The 5th book of the 'Old Testament'(Hebrew Scriptures) is Deuteronomy
The 5th book of the 'New Testament'(Greek Scriptures) is Acts
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The fifth book of the old testament is the fifth book of Moses called Deuteronomy.
It is the first book in the New Testament.
In the book of Genesis, the first book of the Old Testament.
The book of Luke is found in the New Testament (not Old Testament) and is immediately followed by the book of John.
Genesis is the first book of the Old Testament.