Dunno... At least the longest chapter is Psalm 119 and the shortest chapter is Psalm 117. So really it could be anywhere but I bet you could find it in Genesis or the Psalms. At least That's my guess.
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Psalm 119
It is the book of Isaiah.
Under the assumption of 929 chapters in the Old Testament then Job 29 is the middle chapter
Old testament...Genesis New Testament...Matthew
Chapter 7