According to NET.Bible.org the word 'orphan' appears thirty times in The Bible.
You can find the specific verses by searching for the word orphan on the site.
It might depend on what version of the Bible you are looking at, as searches that limit matches to the King James version only find one appearance of the word, when as a universial search returns 30 matches for the word 'orphan' and some matches with related words like fatherless.
The King James Version of the Bible uses the word "fatherless" instead of "orphan." The word "fatherless" is in the King James Version of the Bible 43 times. It is in 43 verses.
The word "orphan" does not appear in the King James Version of the Bible. The plural "orphans" is in the King James Version of the Bible once. Please see the related link below.
The phrase does not appear in the bible.
426 times word without appear in the Bible
Sanctify, sanctifying, and sanctified appear in the bible 15 times.
The King James Version of the Bible uses the word "fatherless" instead of "orphan." The word "fatherless" is in the King James Version of the Bible 43 times. It is in 43 verses.
The word "orphan" does not appear in the King James Version of the Bible. The plural "orphans" is in the King James Version of the Bible once. Please see the related link below.
The word "orphan" does not appear in the King James Version of the Bible. However, the plural word "orphans" is in the King James Version of the Bible 1 time in 1 verse. The King James Version often uses the word "fatherless" instead, 43 times in 43 verses.
426 times word without appear in the Bible
The phrase does not appear in the bible.
Sanctify, sanctifying, and sanctified appear in the bible 15 times.
The word "soteria" does not appear anywhere in the KJV bible.
The word "catholic" does not appear anywhere in the bible.
Seven times in the KJV Bible
18 times
84 times
22 times