Sam Houston was the governor of Texas when that state seceded February 1, 1861. Houston would not take the oath of allegiance to the Confederate States of America or to the new Texas government so the legislature replaced him with Ed Clark who was a staunch secessionist.
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It's when Texas seceded from the Union and joined the Confederacy.
When Virginia's passed an ordinance of secession on April 17, 1861, John Letcher was the state's governor.
withdrawing from the union (answer A ...cough...cough)
South Carolina. Texas.
There were eleven states that seceded by state laws enacted by their legislatures. These were:South CarolinaMississippiFloridaAlabamaGeorgiaLouisianaTexasVirginiaArkansasTennesseeNorth Carolina