The modern Greek alphabet has 24 letters and is derived from the earlier Phoenician alphabet. The greek alphabet has been in use in one form or another since the 8th century BCE. The sixth letter of the modern Greek alphabet is "zeta".
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Digamma. This obsolete letter of the Greek alphabet was primarily used as a Greek numeral.
Our alphabet, called the Roman alphabet, was based on the older Greek alphabet. In Greek, the letter z is the sixth letter. But when the Romans borrowed the Greek letters to form their own alphabet, they didn't need the z, because they didn't have a z sound in their language. Later, many Greek words came into use in the Latin language. So the Romans brought back the z in order to write Greek words, and put the z at the end of their alphabet.
The ninth letter of the Greek alphabet is iota. It is written uppercase Ι, lowercase ι, and the Greek name for the letter is Ιώτα.
The 14th letter of the modern Greek alphabet is xi. It is written uppercase Ξ, lowercase ξ , and the Greek name for the letter is ξι.
Greek, 16th letter