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Alexander the Great was not Persian, he was Macedonian. He took over the Persian Empire and made it into a Macedonian Empire. His successors split up his empire among them and created what we today call the Hellenistic Kingdoms, which included Syria-Mesopotamia, Egypt and Macedonia.
Yes, Czar Peter the Great established St. Petersburg as the capital of his empire in 1703. He wanted a capital city that could also be a seaport.
Great Zimbabwe grew into a empire built on gold trade. it became capital of thriving states.
Sargon,the akkadian king, built the worlds first empire in 2340 B.C. and it was built over sumer (sumer is spelled with only one m if u add two m u will spell summer the season) and the rest of all Mesopotamia.
Constantinople was the capital city of the Eastern Roman Empire, named so after Constantine the Great. It was not an empire.