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Oxygen is not actually explosive. In an acetylene torch, the torch burns the acetylene and the oxygen only facilitates combustion, so it is not burning the oxygen. Hospitals warn of the explosion hazard of oxygen because pure oxygen accelerates the burn of fuel so fast that it is like an explosion. In common air there is roughly 79% nitrogen and 21% oxygen, all fuels must have oxygen to burn and when pure oxygen is introduced the fire then has more oxygen thus it accelerates the fire.

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