Adsorption is a process that occurs when a gas or liquid solute accumulates on the surface of a solid or a liquid (adsorbent), forming a molecular or atomic film (the adsorbate). It is different from absorption, in which a substance diffuses into a liquid or solid to form a solution. The term sorption encompasses both processes, while desorption is the reverse process.
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Yes, physical adsorption typically has a low adsorption enthalpy due to weak van der Waals forces between the adsorbate and adsorbent. These interactions are reversible and non-specific, leading to lower enthalpies compared to chemical adsorption.
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Yes, the adsorption capacity of an adsorbent is influenced by its porosity. A higher porosity provides more surface area for adsorption to occur, resulting in a greater adsorption capacity. Therefore, materials with higher porosity generally exhibit higher adsorption capabilities.
Physical adsorption is reversible because the forces involved are weak van der Waals forces, such as London dispersion forces or dipole-dipole interactions. These forces can be easily disrupted by changes in temperature or pressure, allowing the adsorbate to be released from the adsorbent surface. This reversibility distinguishes physical adsorption from chemical adsorption, which involves stronger, more covalent bonds.
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Lawrence T. Drzal has written: 'Adsorbate-adsorbent interactions by gas adsorption' -- subject(s): Absortion and adsorption, Gases, Adsorption
An adsorption site is a location on a surface where molecules or particles can adhere or bind due to attractive forces. It is where adsorption occurs, where a substance accumulates on the surface of another material. Adsorption sites are important in processes like catalysis, gas separation, and water treatment.
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