Definitely yes.
There is chemical residue left over from the dyeing and manufacturing process - same with new clothes. Your skin is your largest organ and you don't want to be absorbing those chemical compounds.
I would say, even if you are buying organic cotton sheets -
it would still be a good idea to wash them
... and best to wash in soap that has no harsh chemicals - like
http://www.seventhgeneration.com/
this goes for clothes as well!!!
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