No, Valium is not an Opiate. It chemical name is Diazepam and it was developed as a synthetic Valerian root alternative by Doctor, who then discovered its superior qualities as a sedative (not a painkiller like opiates) and called it Valium which is the original Hoffman-LaRoche brand name for the Docs discovery. It is closer to a muscle relaxer than an Opiate. And Opium based drugs or synthesized alternatives are the very best for pain killing effect.
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no, depakote is a derivative of valproic acid, which was originally used as an industrial solvent.
No. Effexor is an SNRI (serotonin-norepinephrine reuptake inhibitor) antidepressant.
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