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Bleach's author, Tite Kubo, has a habit of not officially killing off any of the main protagonists. However, many characters within the show's continuity are killed. Here they are, and be warned now, THERE ARE MASSIVE SPOILERS!

Espada

The 9th Espada, Aaroniero Arruruerie, is killed by Rukia Kuchiki

The 8th Espada, Szayel-Aporro Granz, is killed by Mayuri Kurotsuchi

The 7th Espada, Zommari Leroux, is killed by Byakuya Kuchiki

The 5th Espada, Nnoitra Jiruga, is killed by Kenpachi Zaraki

The 4th Espada, Ulquiorra Cifer, is killed by Ichigo Kurosaki

The 3rd Espada, Tia Harribel, is killed by Sosuke Aizen

The 2nd Espada, Barragan Luisenbarn, is killed by Hachigen Ushoda

The 1st Espada, Coyote Starrk, is killed by Shunsui Kyoraku

Fraccion

Choe Neng Poww is killed by Sajin Komamura

Charlotte Cuulhourne is killed by Yumechika Ayasegawa

Avirama Redder is killed by Izuru Kira

Findor Carias is killed by Shuhei Hisagi

Ggio Vega is killed by Soifon

Nirgge Parduoc is killed by Ggio Vega (in the manga) and Marechiyo Omaeda (in the anime)

Apache is killed by Genryusei Shigekuni Yamamoto

Mila-Rose is killed by Genryusei Shigekuni Yamamoto

Sun-Sun is killed by Genryusei Shigekuni Yamamoto

Shawlong Kufang is killed by Toshiro Hitsugaya

Edrad Liones is killed by Ikkaku Madarame

Nakeem Greendina is killed by Rangiku Matsumoto

Yylfordt Granz is killed by Renji Abarai

Di Roy Linker is killed by Rukia Kuchiki

Lumina is killed by Szayel-Aporro Granz

Shinigami

Kaname Tosen is killed by Shuhei Hisagi

In addition to these casualties, many of the characters are currently grievously injured in the story's continuity, and more deaths may soon be to follow. I hope this helped.

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