episode 130/131 the stadium indiscriminate threatening case.
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i do not know but she did not appeared in 129 because episode 129 is in English dub but I have not seen her yet so for all the morons that are giving the wrong information do some research first
Episodes 501-504
48,49,57,58,77,78,117,118,141,142,166,167,168,174,189,190,191,219,221,222,223,224,238,239,240,263,277,278,291,292,293,323,324,325,326,327,345,381,382,283,406,407,408, 479, 484, 490, 491,515,516,517,521,522,523,554,555 OVAs 1,2,3,6,9 Movies 3,7,10,13, and 14 (As of July 15, 2010)
The best detective conan site would be gogoanime.com. It is good for anime on the whole.
In Episode 1, after the investigation of the roller coaster murder case. After Shinichi seen what they have done, they decided to silence him by giving him a medicine, but it didn't kill him and instead he became Conan.