No, he had a seeming well established girlfriend, but they were not married. In the beginning of the movie they're having dinner together with a bunch of people, and one of the men asks Chuck (Tom Hanks) when he's going to make an honest women of Kelly (Helen Hunt). This implies that no, they were not married at the beginning of the movie. Later Kelly is married to another man, so she and Chuck do not get back together.
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Tom Hanks' character in Castaway worked for Federal Express (FedEx).
"Cast Away" (2000)
FedEx was the courier service.
Bloodied hand print from when he cut himself. Watch the film
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