its not possible in Pokemon Mystery Dungeon red :P u have to play the sky version if u want to start as vulpix (like me :D)
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Riolu, Phanpy or vulpix
No, Vulpix is not a starter Pokemon in any of the official core games, but it can be the Hero Pokemon (the player) in the Pokemon Mystery Dungeon sequels by having the Relaxed nature and choosing to be a female in the game.
you need a fire stone then you go to luminous spring and evolve
bulbasaur, charmander, squirtle, pikachu, vulpix, eevee, chikorita, cyndaquil, totodile, phanphy, treecko, torchic, mudkip, skitty, turtwig, chimchar, piplup, shinx and riolu meowth and munchlax are only available as partners
the answer to this question is that you don't evolve it after you finish the game go in the hole where the wishcash pond is and give the mysterious voice a fire stone and you can evolve vulpix