Go to the Eastern Sea. Go into the cave. Go directly down. There is way entrance there. However, the water spurting from the entrance is too strong. Go the other way until you see an entrance that leads upward. Go through it. Octillery is there.
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The newest Pokemon ranger game is Pokemon ranger: Guardian Signs.
It is in the Sky Fortress.
you don't catch it
on the route where you chase the Pokemon pinchers to their sub hideout
go east from tilt village