No. They've been together for years and none have cheated.
EDIT A very stupid little girl thought it would be a good idea to come on here and edit my answer to say that Frank has been having an affair with some randomer. I have deleted it because idiotic little girls that like to spread untruerumours ruin fan communities. Thank you.
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Frank Iero is married. To who, I don't know. ----Edit---- Frank Iero is married to Jamia Nestor, and has twins :)
Jamia Iero (Nestor), wife of Frank Iero (of My Chemical Romance), was born on February 23, 1982. This puts her age at 22.
Jamia Nestor is Frank Iero's wife
They met in high school and have been dating since... Jamia sold all of MCR's merch early on in the bands beginning. Frank and Jamia were married on the 9th of March, 2008.
Yes. She will be expecting the delivery in Summer of 2010, I believe. Her exact due date, however, I do not know.