There are several words in the English language that end with the letter v. Some of these words include improv, perv, shiv, spiv, maglev, and schav.
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Here are 39 words ending in V! I don't know if they are valid scrabble words or not... http://www.findtheword.info/resultat.php?stype=ends&sword=V
Six letter words ending in V are improv and maglev.
vacantvagrantvaliantvaletvariantvarmintvatvetvigilantviolentvomit
Slav, Kiev, Lvov
There are no English words that meet the criteria.