Yes but you can use the attack mean look and it won't run. Golbat learns it at level 38.
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If its a Pokemon that runs away like entei, raikou and suicune weaken it when you find it when it shows up again it will still be weak now throw a ultra ball if you fail keep trying!
If you've already scattered the Legendary Dogs, then Entei will be wandering with Raikou across Johto. Your Pokegear has a map with their heads on it - where the head's located, that's where a Dog is. You have to be on the same route with Entei, then just wander in the grass until he appears. He may move, in which case you'll have to follow them to the next route. I suggest a Pokemon with an ability that will prevent Entei from fleeing, as well as possibly a status ailment and obviously something to knock its health down with. Although if you use a move that keeps him from running, he'll use roar to get away
Yes, five: Zapdos, Articuno, Moltres, Mewtwo, and ONE of the Johto Legendary Trio (entei, raikou, or suicune) the johto legend depends on the starter you choose. Also, Deoxys, Lugia, and Ho-oh were given away in events.
Entei can be captured without the Master Ball however it's much more difficult. Once you find Entei attack it and it should run away. Now you must find it again when it appears its HP should still be lowered so now is your chance to capture it with any other ball you have.
1.use your pokegear then find them 2.when you find him walk [if you fly they will run away] 3.if you have a pokemon that knows mean look then use it 4. attack usind false swipe 4. captureyou have to run into them in the wild grass they show up on pokegear map