Unfortunately no, assuming Butterfree acts the same way normal butterflies do. After Butterfree mates, it will die. But I suppose you can always hope...
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Butterfree found a soul mate and ash let it go.
Butterfree is a Bug-Flying-type that Ash Ketchum originally used in the TV series. It's evolved from Metapod from Caterpie. Butterfree is rivals with Beedrill.
No, butterfree does not evolve. Butterfree is the last stage evolution of caterpie. Caterpie, Metapod and then Butterfree.
No, Butterfree cannot learn Fly.
Butterfree does not evolve, a Caterpieevolves into a Metapod and then the Metapod evolves into Butterfree.