Probably zoroark since its a dark type and psycic move cant affect it.
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Zekrom he is a legendary
ZOROARK
This is an opinion question, so opinions will vary by person. I personally prefer Mega Mewtwo Y, but that's just my opinion.
You do if you want to catch the female Zoroark event. However, if you have a Celbi and get the Zorua,you can evolve it in to a Zoroark.
Probably Mewtwo, because you catch Ho-oh at level 40, and catch Mewtwo at level 70. Mewtwo is stronger, and a more powerful pokemon. Ho-oh won't be enough to take on Red, unless you train it.