well, that depends on which level the Pokemon is. A manectric of lvl 100 is stronger dan a pikachu of lvl 32. But a pikachu of lvl 100 is stronger than a manectric of lvl 32. So if you want your pikachu to be stronger than your manectric, you just have to train it to a higer lvl than manectric or go and check their stats when they are at level 100 and the Pokemon with the higher stats is better. But when you give a Pokemon a rare candy, their stats become lower, so its better to train them in a Pokemon figh, so try training them against water or flying types.
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some good electric Pokemon catches in RUBY/SAPPHIRE would be electrode, manectric and magneton (Electrode and Magneton are rare but Manectric is Uncommon) there is also voltorb, pikachu, magnemite, chinchou, lanturn e.t.c
pikachu with light ball is better
Manectric can learn TM24- Thunderbolt.
Pikachu
No, Manectric is the final evolution of Electrike, which evolves at level 26.