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Spoink evolves at level 32.
Spoink evolves into Grumpig when it reaches level 32 or higher. Unless an Everstone is equiped to it or you press 'B' during the evlution, Spoink shouldn't evolve.
It is suppose to evolve at the Level of 20,but if you want it to evolve later it can evolve anything after it is at Level 20.
It will evolve by level. Teddiursa will evolve into a Ursaring at level 30.
They evolve at level 36