The letter that directly precedes the letter "N" in the English alphabet is the letter "M". The letter "M" is the 13th letter of the alphabet, while "N" is the 14th letter. Directly following the letter "N" is the vowel "O". The letter "O" is also a vowel, and is the 15th letter of the alphabet. It is the 4th vowel in the alphabet.
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Smoke
any vowel after the fourth vowel
The answer is not the obvious "e" the word Vowel in it self is "vowel" being 6th, so it is the letter a.
If u mean starts with a vowel and ends in a vowel, then Avalanche?
Stretch is a 7 letter word with e as the only vowel. Twelfth is another 7 letter words containing only one vowel.