rhypirior loves protector
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I believe that Rhydon loves the Protector, but I only found that out by trading it with the Protector on
catch a rhydon, give it the protector and trade it it will evolve into rhyperior and you will lose your protector
When looking at the item, it does say "a Pokemon loves this item". It is a hint to give a Pokemon that item. Well that Pokemon is a rhydon. Give a rhydon that item to hold. Trade it and see what happens...
you can't get a protector in Emerald. The Protector evolves Rhydon into Rhyperior, who is a Generation IV (Sinnoh) Pokemon.
In Pokemon Diamond and Pearl, a Protector can be found on Route 228. In Pokemon Platinum, a Protector can be found on Iron Island.