Well there is only about 3 Pokemon that evolve with the sun stone and 2 in Pokemon sapphire gloom and sunkern which turn into bellossom and sunflora.
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You should evolve sunkern when you are in need of a strong grass type, and when you have a spare sun stone on hand. In Pokemon Ruby, Sapphire, and Emerald, you can get a sun stone in the Rocket Institution in Mossdeep City.
gloom elvolves with sun stone
The Sun Stone is an evolutionary stone that allows certain Pokemon to evolve. The following Pokemon can evolve using this stone: Gloom, Sunkern, Cottonee, Petilil, and Heliotile.
Gloom will evolve to Bellossom, and Sunkern will evolve into Sunflora using a Sun Stone.
in order to evolve Roselia you have to use a sun stone on it You use a shiny stone, not a sun stone.