you teach a Pokemon that move or use a TM
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The moves Block and Mean Look do not exist as TMs on Pokemon Diamond. Block and Mean Look have yet to become a TM in any of the Pokemon games so far if ever.
yes why yes there is
If you evolve zubat to golbat it learns mean look at level 33
on the ground somewhere or i think in the mall that's in that one city.
As far as I know you can only get it with Pokemon that already have it. But i expect you could find one in dark places like caves.