Make sure you get the S.S Anne ticket from Bill and head for Vermillion City. You'll find the S.S Anne ready to leave, but it won't until you get the HM Cut from the captain who is seasick. Make sure you battle the trainers and get the items on the ship first. And be ready to face your rival before you reach the captain. Once you get the HM and leave the ship, it'll sail away and won't return forever.
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where to get surf in Pokemon fire red
use cut
you get it from the captin on the s.s. ann
charizard
use cut