You can't catch in in Leaf Green.
You must trade Growlithe from Fire Red and Evolve it with Fire Stone to get Arcanine.
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Arcanine is the evolved form of Growlithe. Neither of them can be caught in the wild on Leaf Green. Growlithe is a Pokemon Fire Red exclusive pokemon. To be able to evolve it, give it a Fire Stone and then trade it to your Leaf Green game.
in leaf green you cant find ekans, arbok, oddish, gloom, vileplume, psyduck, golduck, growlithe, arcanine, shellder, cloyster, scyther, and electobuzz but you can trade them from fire red.
I never heard of it so find a better game then green as leaf
Usually you can find it in seafoam islands.
leaf green only.