you have a chance to get them when you use honey on honey trees.
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You have to put honey on a tree and wait a certain time.
you put honey on a honey tree and wait 4 like a day then u might find a heracross. if you don't u can trade with ur friends or use the gts system thing.
You can catch heracrosses by headbutting trees. But in order to have a powerful heracross your going to have to do some training. sorry.
Heracross is in the Safari Zone. Use an Acro Bike to get across the poles (white lines) and go North. The areas there hold Heracross (they are rare and hard to catch so beware).
on route 6665