the underground path. it's near the radio tower. go all the way to the right, there should be a room where a guy can take photos of your pokemon wearing different accessories. if your'e talking about photographer cameron, he should be in the underground path.
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In Pokemon Soulsilver, you can get a Net Ball from Johto in Goldenrod City. You have to win it from the Goldenrod Dept. Store lottery.
Go south of Goldenrod city.
Both Goldenrod City and Celadon City have Supermarkets.
the shop is in goldenrod city.
The day care is between Ilex Forest and Goldenrod City.