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Yes, Deino can learn Draco Meteor from the appropriate Move Tutor.
you need to go to the draco meteor move tutor near celestic town
You go to the move tutor place and the women would teach your dragon type Draco meteor.
Dragonite can not learn Draco Meteor by leveling up. You teach it with a Move Tutor.
She will teach Draco meteor an infinite number of times so long as the Pokemon is part dragon type with happiness maxed out.