it will find near slate port city
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you cant but you can in diamond and pearl but on Pokemon emerald you can only get super pop or whatever its called at the beach place on the sand in the house.
The first item shop you go to is in sand gem town.it has a blue roof.
to get a poison barb in Pokemon emerald(*1), first get a Pokemon that knows the move THIEF(*2). next you go into the desert sand in route 111, (the sand acts like grass so wild Pokemon will appear while in it) there is a chance that a wild cacnea will attack you. if you are super lucky(*3) the cacnea will be holding a poison barb which is used for increasing the power of poison type moves like ACID. Hope it helps, from Pokemon emerald trainer: Coolguy (*1) wild roslia also hold it in ruby or Sapphire (*2) it is also a TM that you can get in slateport city (*3) there is a 5% chance it will hold a poison barb (*4) I am sorry for any misspellings I may have made
Obtain the Go-Goggles from May/Brenden in Lavaridge Town after you defeat the Gym Leader.
Find a Sandshrew in the desert at Route 111, 113, or the Mirage Tower, and evolve it into a Sandslash at level 22.