Cianwood City
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The fifth gym can be Jasmine or Chuck. No one is blocking any of the gyms. Although Jasmine might not be at the gym until you help the injured Pokemon.
The fifth gym is in petalburg city
The gym leader is not at the gym and that is why we cannot enter the gym.
There is no way, because there is no such thing as Pokemon Frosty.
You get it when you battle your dad which is the fifth gym