In Lilycove. The big skyscraper is the pokemon mart. Just go up the floors, and they sell different items.
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In lilycove city.
To the Rustboro girl,you will need to say a big code.Search in google:"Pokemon Emerald Secret Word Generator"
ITs actually the department store, and it's in Lillycove
its not an emerald its RAYQUAZA the main legendary Pokemon in Pokemon emerald.
It is the big building in the north-west of rustboro city.