Fight Ankous in the Barbarian Stronghold (west of varrock)
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what i did was train your team in mt. cornet or around snowpoint city because there is really good Pokemon around that area. hope this helps :)
The best place to train a lvl 20-30 Lucario is up by Snowpoint city. Fighting types like him are really good there.
At the ppl in the sea or 1 island
sky pillar the further to the top you get the stronger the Pokemon get. on the floor just under rayquaza u can find lvl 50 claydols. on the top is rayquaza lvl 70. its almost unstoppable at lvl 100
you should train sycher against fire and pshcik pokemon:D