Ground Floor in the Goldenrod Radio Tower. Talk to the woman at the counter.
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you really cant beat the lottery in goldenrod city without a cheat code.....i advise you to go to (cheatsguru.com)
You can get it from Mr. Pokemon in exchange for a Red Scale, or the Goldenrod Radio Tower Lottery Corner. If you match 3 digits, you get an EXP. Share.
In Pokemon Soulsilver, you can get a Net Ball from Johto in Goldenrod City. You have to win it from the Goldenrod Dept. Store lottery.
At the top of the city, upper to Poke Center.
in the radio tower