Ground Floor in the Goldenrod Radio Tower. Talk to the woman at the counter.
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you really cant beat the lottery in goldenrod city without a cheat code.....i advise you to go to (cheatsguru.com)
You can get it from Mr. Pokemon in exchange for a Red Scale, or the Goldenrod Radio Tower Lottery Corner. If you match 3 digits, you get an EXP. Share.
At the top of the city, upper to Poke Center.
In Pokemon Soulsilver, you can get a Net Ball from Johto in Goldenrod City. You have to win it from the Goldenrod Dept. Store lottery.
in the radio tower