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AOSS is a function of certain routers that allow it to set up internet connections automatically. So what happens is, you select AOSS connection on the DSi, press the AOSS button on the router, and the two will communicate, setting up and configuring the optimal connection.
The PS3 does not have a AOSS button
the Aoss is located on your router and the PS3 does not have a router and does not have a button.
The button is on your router
The AOSS button is something on a wireless router, it's not on the PSP itself.