In the sea, where the water is darker than the surrounding areas.
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Dive is not an HM in leafgreen you can't get it unless you trade a Pokemon that knows Dive from ruby or sapphire or emerald but it will not work in leafgreen unless your in battle.
Dive is not an HM available in Leafgreen. If you want to teach a pokemon Dive trade it to any of the Hoenn Region pokemon games (Ruby, Sapphire, Emerald) and use the HM Dive to teach the move and then you can trade it back. NOTE you cannot use Dive outside of battle just like Ruby, Sapphire, Emerald since it's not an HM instead it's a regular move that can be removed either by the Move Deleter or by teaching a different move.
Dive is not an HM in Pokemon firered or leafgreen however if you trade a Pokemon that knows dive from ruby or sapphire or emerald now you have a Pokemon that knows dive But you can't dive underwater in firered or leafgreen because it wasn't invented in the kanto region.
Use dive near that one huge rock RIGHT UP AGAINST THE WALL AND IN THE CENTER There should be an entrance underneath.
Steven gives it to you in mossdeep city. You have to beat the mossdeep gym before you can use it. They are Psychic types so be careful.