you need to get an evee which bebe gives you in hearthome city. make evee friendly in the night by a berry,poffin,items and stuff
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If you go onto that muddy trail past pastoria city, you will see a collector trainer, battle him and he has a Umbreon and a Espeon
sorry you cant, you have to evolve your evee during the night it will be either a umbreon or a espeon. so its the matter of luck on getting the one you want.
on national pokedex its umbreon
you have to level him up at night
Collector Dean on Route 212 west of Pastoria City is a Collector with an Umbreon that is level 27.