You go to Azalea town and headbutt the trees in Azalea town or on route 33.
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Headbutt trees near mountains
You can obtain an Aipom by headbutting trees.
aipom's evole is a Pokemon from the next generation after emerald so its impossible to receive him.
aipom does not evolve inpokemon emerald
Aipom is #190 in the national pokedex, and it is a Normal type Pokemon.