In Iron Island. before entering Registeel cave you found a poke ball with the shiny stone. you can get a shiny stone in route 228 too.
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There is a shiny stone at the end of Iron Island.
You can find a Shiny Stone in Route 228 in Pokemon Diamond and Pearl. In Pokemon Platinum, you can also find a Shiny Stone on Iron Island.
Shiny stone is used to evolve Roselia to Roserade Togetic to Togekiss
Shiny Stone
You can find shiny stones on route 228 and Iron island