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You can give them to your Pokemon when you migrate from Ruby and Sapphire. You can also find them on your pokewalker on any of the beaches. They are more common in the routes that take longer to unlock. I haven't seen any in the actual game.
Go to www.pokemonwifi.org, they will answer any questions you have.

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use thief on wild luvdisc that swarm next to beginning town
You can find them in one of the routes on the pokewalker.
Rock smash the rocks in the Ruins of Alph or use the Dowsing Machine.

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