In any of the gates eading in and out of cities e.g The North East gate of Nimbassa cit.
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Joltic the electric bug pokemon found in chargestone cave.
The new Electric Pokemon introduced in Black and White are: Blitzle & Zebstrika Emolga Joltik & Galvantula Tynamo, Eelektrik, & Eelektross Stunfisk Thundurus Zekrom
When the electric boards say there is an outbreak of Pokemon in route 10 that is where you can get one
Super effective on Electric---Ground Super effective on Flying---Ice, Rock, Electric If you mean super effective on an electric/flying type: rock and ice.
Ground types are great against electric types so find yourself a decent ground type Pokemon and train it a bit then use it.